Jeon, In-Yup and Choi, Eun-Kyoung and Bae, Seo-Yoon and Baek, Jong-Beom (2010) Edge-Functionalization of Pyrene as a Miniature Graphene via Friedel–Crafts Acylation Reaction in Poly(Phosphoric Acid). Nanoscale Research Letters, 5 (10). pp. 1686-1691.
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The feasibility of edge-functionalization of graphite was tested via the model reaction between pyrene and 4-(2,4,6-trimethylphenyloxy)benzamide (TMPBA) in poly(phosphoric acid) (PPA)/phosphorous pentoxide (P2O5) medium. The functionalization was confirmed by various characterization techniques. On the basis of the model study, the reaction condition could be extended to the edge-functionalization of graphite with TMPBA. Preliminary results showed that the resultant TMPBA-grafted graphite (graphite-g-TMPBA) was found to be readily dispersible in N-methyl-2-pyrrolidone (NMP) and can be used as a precursor for edge-functionalized graphene (EFG).
|Subjects:||Material Science > Functional and hybrid materials|
|Deposited On:||31 Dec 2010 02:57|
|Last Modified:||31 Dec 2010 02:57|
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