Nano Archive

Composition distributions in FePt(Au) nanoparticles

Srivastava, C. and Nikles, D. E. and Harrell, J. W. and Thompson, G. B. (2010) Composition distributions in FePt(Au) nanoparticles. Journal of Nanoparticle Research, 12 (6). pp. 2051-2056.

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Ternary alloy FePt(Au) nanoparticles were prepared by the co-reduction of platinum(II) acetylacetonate and gold(III) acetate and the thermal decomposition of iron pentacarbonyl in hot phenyl ether in the presence of oleic acid and oleylamine ligands. This gave spherical particles with an average diameter of 4.4 nm with a range of diameters from approximately 1.6–9 nm. The as-synthesized particles had a solid solution, face-centered-cubic structure. Though the average composition of the particles was Fe44Pt45Au11, individual particle analysis by Scanning Transmission Electron Microscopy–X-ray Energy Dispersive Spectroscopy showed a broad distribution in composition. In general, smaller-sized particles tended to have a lower amount of Au as compared to larger-sized particles. As the Au content increased, the ratio of Fe/Pt widened.

Item Type:Article
Uncontrolled Keywords:FePt - Nanoparticles - Compositional distributions - Synthesis
Subjects:Material Science > Nanostructured materials
ID Code:9464
Deposited By:SPI
Deposited On:02 Aug 2010 17:42
Last Modified:02 Aug 2010 17:42

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