Nano Archive

Single-walled carbon nanotube formation on iron oxide catalysts in diffusion flames

Unrau, Chad J. and Axelbaum, Richard L. and Fraundorf, Phil (2010) Single-walled carbon nanotube formation on iron oxide catalysts in diffusion flames. Journal of Nanoparticle Research, 12 (6). pp. 2125-2133.

Full text is not hosted in this archive but may be available via the Official URL, or by requesting a copy from the corresponding author.


Single-walled carbon nanotubes (SWCNTs) are shown to grow rapidly on iron oxide catalysts on the fuel side of an inverse ethylene diffusion flame. The pathway of carbon in the flame is controlled by the flame structure, leading to formation of SWCNTs free of polycyclic aromatic hydrocarbons (PAH) or soot. By using a combination of oxygen-enrichment and fuel dilution, fuel oxidation is favored over pyrolysis, PAH growth, and subsequent soot formation. The inverse configuration of the flame prevents burnout of the SWCNTs while providing a long carbon-rich region for nanotube formation. Furthermore, flame structure is used to control oxidation of the catalyst particles. Iron sub-oxide catalysts are highly active toward SWCNT formation while Fe and Fe2O3 catalysts are less active. This can be understood by considering the effects of particle oxidation on the dissociative adsorption of gas-phase hydrocarbons. The optimum catalyst particle composition and flame conditions were determined in near real-time using a scanning mobility particle sizer (SMPS) to measure the catalyst and SWCNT size distributions. In addition, SMPS results were combined with flame velocity measurement to measure SWCNT growth rates. SWCNTs were found to grow at rates of over 100 μm/s.

Item Type:Article
Uncontrolled Keywords:Single-wall carbon nanotubes - Diffusion flames - Differential mobility analyzer - Iron oxide catalyst - Oxy-fuel combustion
Subjects:Material Science > Nanofabrication processes and tools
ID Code:9457
Deposited By:SPI
Deposited On:02 Aug 2010 16:11
Last Modified:02 Aug 2010 16:11

Repository Staff Only: item control page