Sadeghzadeh, Homa and Morsali, Ali and Yilmaz, Veysel T. and Büyükgüngör, Orhan (2010) Synthesis of PbO nano-particles from a new one-dimensional lead(II) coordination polymer precursor. Materials Letters, 64 (7). 810 - 813.
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Official URL: http://www.sciencedirect.com/science/article/B6TX9...
A new Pb(II) one-dimensional coordination polymer, [Pb(µ-NO2)(µ-pyc)(H2O)]n (1), Hpyc = 2-pyridinecarboxylic acid} was prepared and characterized by elemental analyses, powder XRD diffraction and IR spectroscopy. Compound 1 was structurally characterized by single-crystal X-ray diffraction and one-dimensional coordination polymer with coordination environment of PbNO6. The thermal stability of compound 1 showed that compound 1 decomposes at 110–500 °C and the final product is PbO. This polymeric precursor has been used to make PbO nano-particles using two different surfactants. The new nano-structure was characterized by scanning electron microscopy and X-ray powder diffraction. This study demonstrates that the coordination polymers may be suitable precursors for the preparation of nanoscale materials.
|Uncontrolled Keywords:||Crystal structure; Thermal properties; Nano-materials|
|Subjects:||Material Science > Nanostructured materials|
|Deposited On:||08 Jun 2010 16:57|
|Last Modified:||08 Jun 2010 16:57|
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