Nano Archive

Self-assembly of molecules of metal macrocyclic compounds in nanoreactors on the basis of biopolymer-immobilized matrix systems

Mikhailov, O. (2010) Self-assembly of molecules of metal macrocyclic compounds in nanoreactors on the basis of biopolymer-immobilized matrix systems. Nanotechnologies in Russia, 5 (1). pp. 18-34.

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Official URL: http://dx.doi.org/10.1134/S1995078010010027

Abstract

Abstract The problems concerned with the processes of self-assembly of 3d-element aza-and thiazamacrocyclic complexes that happen in nanoreactors on the basis of metal hexacyanoferrate (II) gelatin-immobilized matrices under their contact with water solutions containing various (N, O, S)-donor atomic ligands and organic compounds having one or two carbonyl groups have been considered. It was noted that, in a series of cases, the variety of metal macrocyclic compounds obtained at self-assembly in such specific conditions considerably differs from that of metal macrocycles formed at the conditions traditional for chemical synthesis.

Item Type:Article
ID Code:9203
Deposited By:Prof. Alexey Ivanov
Deposited On:13 May 2010 12:53
Last Modified:13 May 2010 13:19

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