Marquez, Muñoz-Márquez and Fernández, Asunción and Crespo, Patricia and Hernando, Antonio and Lucena, Raquel and Conesa, José (2010) Permanent magnetism in phosphine- and chlorine-capped gold: from clusters to nanoparticles. Journal of Nanoparticle Research, 12 (4). pp. 1307-1318.
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Official URL: http://dx.doi.org/10.1007/s11051-010-9862-0
Magnetometry results have shown that gold NPs (∼2 nm in size) protected with phosphine and chlorine ligands exhibit permanent magnetism. When the NPs size decreases down to the subnanometric size range, e.g. undecagold atom clusters, the permanent magnetism disappears. The near edge structure of the X-ray absorption spectroscopy data points out that charge transfer between gold and the capping system occurs in both cases. These results strongly suggest that nearly metallic Au bonds are also required for the induction of a magnetic response. Electron paramagnetic resonance observations indicate that the contribution to magnetism from eventual iron impurities can be disregarded.
|Deposited By:||Prof. Alexey Ivanov|
|Deposited On:||13 May 2010 12:53|
|Last Modified:||13 May 2010 13:19|
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