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Enhanced π-π interactions between a C60 fullerene and a buckle bend on a double-walled carbon nanotube

Gorantla, Sandeep and Avdoshenko, Stanislav and Borrnert, Felix and Bachmatiuk, Alicja and Dimitrakopoulou, Maria and Schaffel, Franziska and Schönfelder, Ronny and Thomas, Jurgen and Gemming, Thomas and Warner, Jamie H. and Cuniberti, Gianaurelio and Eckert, Jurgen and Buchner, Bernd and Rummeli, Mark H. (2010) Enhanced π-π interactions between a C60 fullerene and a buckle bend on a double-walled carbon nanotube. Nano Research, 3 (2). pp. 92-97.

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Abstract

In situ low-voltage aberration corrected transmission electron microscopy (TEM) observations of the dynamic entrapment of a C60 molecule in the saddle of a bent double-walled carbon nanotube is presented. The fullerene interaction is non-covalent, suggesting that enhanced π-π interactions (van der Waals forces) are responsible. Classical molecular dynamics calculations confirm that the increased interaction area associated with a buckle is sufficient to trap a fullerene. Moreover, they show hopping behavior in agreement with our experimental observations. Our findings further our understanding of carbon nanostructure interactions, which are important in the rapidly developing field of low-voltage aberration corrected TEM and nano-carbon device fabrication.

Item Type:Article
Subjects:Material Science > Nanochemistry
Material Science > Nanostructured materials
ID Code:8808
Deposited By:CSMNT
Deposited On:25 Aug 2010 10:38
Last Modified:25 Aug 2010 10:42

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