DePrince, A. Eugene and Hinde, Robert J. (2010) Accurate Computation of Electric Field Enhancement Factors for Metallic Nanoparticles Using the Discrete Dipole Approximation. NANOSCALE RESEARCH LETTERS, 5 (3). pp. 592-596. ISSN 1931-7573 (Print) 1556-276X (Online)
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We model the response of nanoscale Ag prolate spheroids to an external uniform static electric field using simulations based on the discrete dipole approximation, in which the spheroid is represented as a collection of polarizable subunits. We compare the results of simulations that employ subunit polarizabilities derived from the Clausius Mossotti relation with those of simulations that employ polarizabilities that include a local environmental correction for subunits near the spheroids surface [Rahmani et al. Opt Lett 27: 2118 (2002)]. The simulations that employ corrected polarizabilities give predictions in very good agreement with exact results obtained by solving Laplaceâs equation. In contrast, simulations that employ uncorrected ClausiusâMossotti polarizabilities substantially underestimate the extent of the electric field âhot spotâ near the spheroidâs sharp tip, and give predictions for the field enhancement factor near the tip that are 30 to 50% too small.
|Subjects:||Physical Science > Nanophysics|
Physical Science > Nano objects
Physical Science > Photonics
|Deposited By:||M T V|
|Deposited On:||21 Apr 2010 14:31|
|Last Modified:||21 Apr 2010 14:31|
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