Botello-Mendez, Andres R. and Lopez-Urias, Florentino and Terrones, Mauricio and Terrones, Humberto (2010) Enhanced ferromagnetism in ZnO nanoribbons and clusters passivated with sulfur. Nano Research, 1 (5). pp. 420-426. ISSN 1998-0124 (Print) 1998-0000 (Online)
Official URL: http://www.springerlink.com/content/620k6601622358...
Inspired by recent experimental results, the electronic and magnetic properties of sulfur-passivated ZnO clusters and zigzag nanoribbons have been studied using first principles calculations in the framework of the local spin density approximation. In the case of the ZnO nanoribbons, the sulfur atoms or thiol groups were attached in different ways to the zinc or oxygen atoms located at the edges, whereas in clusters, the sulfur atoms were set on the surface, mainly interacting with atoms with low-coordinate number. After an exhaustive atomic relaxation, we found that a magnetic moment emerges in zigzag nanoribbons both with and without sulfur-passivation on the edges. However, the magnitude of the magnetic moment is very sensitive to sulfur passivation. In particular, we found that when sulfur is attached to the zinc atoms in an alternating fashion along the ribbon edges, the magnetic moment is a maximum (1.4 ÂµB/unit cell). In the case of clusters, we found that the Zn15O15 cluster exhibits a high spin moment of 5.5 ÂµB when capped with sulfur atoms. Our calculations indicate that sulfur-passivating of ZnO nanosystems could be responsible for recently observed ferromagnetic responses.
|Subjects:||Physical Science > Nanophysics|
Physical Science > Nano objects
Material Science > Nanochemistry
Material Science > Nanostructured materials
|Divisions:||Faculty of Engineering, Science and Mathematics > School of Physics|
Faculty of Engineering, Science and Mathematics > School of Chemistry
|Deposited On:||06 Apr 2010 05:43|
|Last Modified:||14 May 2010 14:16|
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