Nano Archive

Thin films of ruthenium phthalocyanine complexes

Rawling, Tristan and Austin, Christine E. and Hare, Dominic and Doble, Philip A. and Zareie, Hadi M. and McDonagh, Andrew M. (2009) Thin films of ruthenium phthalocyanine complexes. Nano Research, 2 (9). pp. 678-687.



Four new ruthenium phthalocyanine complexes bearing axial ligands with thioacetate groups that facilitate thin film formation on gold surfaces are presented. Scanning tunnelling microscopy (STM) images and surface coverage data obtained by solution inductively coupled plasma mass spectrometry (ICP-MS) experiments show that peripheral and axial ligand substituents on the complexes have a significant effect on their surface coverage. A laser ablation ICP-MS technique that provides information about thin films across macro-sized areas is described here for the first time. Using the technique, the maximum surface coverage of a ruthenium phthalocyanine complex was found to occur within one minute of gold substrate immersion in the complex-containing solution.

Item Type:Article
Divisions:Faculty of Engineering, Science and Mathematics > School of Physics
Faculty of Engineering, Science and Mathematics > School of Chemistry
ID Code:8047
Deposited By:Prof. Alexey Ivanov
Deposited On:06 Feb 2010 11:11
Last Modified:17 Feb 2010 05:12

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