Nano Archive

Nanoparticle stability from the nano to the meso interval

Mayoral, Alvaro and Barron, Hector and Estrada-Salas, Ruben and Vazquez-Duran, Alma and José-Yacamán, Miguel (2009) Nanoparticle stability from the nano to the meso interval. nanoscale .

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Abstract

Nanoparticles are the cornerstone of nanotechnology. Their crystal structure and relation to shape are still open problems despite a lot of advances in the field. The classical theory of nanoparticle stability predicts that for sizes <1.5–2 nm the icosahedral structure should be the most stable, then between around 2–5 nm, the decahedral shape should be the most stable. Beyond that, face-centered-cubic (FCC) structures will be the predominant phase. However, in the experimental side, icosahedral (Ih) and decahedral (Dh) particles can be observed much beyond the 5 nm limit. In fact, it is possible to find Ih and Dh particles even in the mesoscopic range. Conversely, it is possible to find FCC particles with a size <1.5 nm. In this paper we review a number of the mechanisms proposed in the literature that allow the stabilization of nanoparticles. Some of the mechanisms are very interrelated and it becomes difficult to distinguish between them.

Item Type:Article
Subjects:Material Science > Nanochemistry
ID Code:7919
Deposited By:CSMNT
Deposited On:03 Jan 2010 03:42
Last Modified:03 Jan 2010 03:42

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