Nano Archive

Nano-tribological characteristics of TiO2 films on 3-mercaptopropyl trimethoxysilane sulfonated self-assembled monolayer

Li, J and Sheng, XH (2009) Nano-tribological characteristics of TiO2 films on 3-mercaptopropyl trimethoxysilane sulfonated self-assembled monolayer. BULLETIN OF MATERIALS SCIENCE , 32 (5). pp. 481-286. ISSN 0250-4707

Full text is not hosted in this archive but may be available via the Official URL, or by requesting a copy from the corresponding author.

Abstract

Silane coupling reagent (3-mercaptopropyl trimethoxysilane (MPTS)) was used to prepare twodimensional self-assembled monolayer (SAM) on silicon substrate. The terminal -SH group was in situ oxidized to -SO3H group to endow the film with good chemisorption ability. Then TiO2 thin films were deposited on the oxidized MPTS-SAM to form composite thin films, making use of the chemisorption ability of the -SO3H group. Atomic force microscope (AFM) and contact angle measurements were used to characterize TiO2 films. Adhesive force and friction force of TiO2 thin films and silicon substrate were measured under various applied normal loads and scanning speed of AFM tip. Results showed that the friction force increased with applied normal loads and scanning speed of AFM tip. In order to study the effect of capillary force, tests were performed in various relative humidities. Results showed that the adhesive force of silicon substrate increases with relative humidities and the adhesive force of TiO2 thin films only increases slightly with relative humidity. Research showed that surfaces with more hydrophobic property revealed the lower adhesive and friction forces.

Item Type:Article
Subjects:Material Science > Tunnelling and microscopic phenomena
ID Code:7883
Deposited By:CSMNT
Deposited On:25 Dec 2009 15:01
Last Modified:25 Dec 2009 15:01

Repository Staff Only: item control page