Ahmadzadi, H. and Marandi, F. and Morsali, A.. (2009) Structural and X-ray powder diffraction studies of nano-structured lead(II) coordination polymer with eta(2) Pb center dot center dot center dot C interactions. JOURNAL OF ORGANOMETALLIC CHEMISTRY , 694 (22). pp. 3565-3569. ISSN 0022-328X
Full text is not hosted in this archive but may be available via the Official URL, or by requesting a copy from the corresponding author.
Official URL: http://www.sciencedirect.com/science?_ob=ArticleUR...
A new nano-sized Pb(II) one-dimensional coordination polymer with eta(2) Pb-C interactions, [Pb-2 (mu(3)-ba)(2)(mu(2)-ba)(2)](n) (1) [ba = benzylacetylacetonate] has been synthesized and characterized by SEM, X-ray powder diffraction, IR spectroscopy and elemental analyses. Single-crystal X-ray diffraction shows the coordination number of Pb(II) ions is seven and the lead atoms have hemidirected coordination sphere containing involving Pb center dot center dot center dot C interactions, C2O7Pb. PbO nanoparticles were obtained by calcinations of the nano-sized compound 1 at 600 degrees C. (C) 2009 Elsevier B. V. All rights reserved.
|Subjects:||Physical Science > Nanophysics|
Physical Science > Nano objects
Material Science > Nanochemistry
Material Science > Nanostructured materials
|Divisions:||Faculty of Engineering, Science and Mathematics > School of Physics|
Faculty of Engineering, Science and Mathematics > School of Chemistry
|Deposited On:||04 Nov 2009 07:48|
|Last Modified:||04 Nov 2009 07:48|
Repository Staff Only: item control page