Li, Hongyan and Liu, Gang and Liu, Bin and Chen, Wei and Chen, Shoutian (2007) Dielectric properties of polyimide/Al2O3 hybrids synthesized by in-situ polymerization. Materials Letters, 61 (7). 1507 - 1511.
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Official URL: http://www.sciencedirect.com/science/article/B6TX9...
Polyimide/nano-Al2O3 hybrids were prepared via simple in-situ polymerization and the thermal imidation routes. The hybrids film was characterized by transmission electron microscope (TEM) and infrared spectrum (IR). The dielectric behaviors of the composites were investigated as a function of the concentration of the Al2O3 nanoparticles. The results show that, at ± 980 V (bipolar), the corona-resistant life to the breakdown of polyimide with nano-Al2O3 loading of 30% is 93 min which is over 10 times longer than that of the unfilled film. Such large enhancement may originate from the shielding, thermal conduction and thermal stability effects of the nano-Al2O3 layer. As the nano-Al2O3 loading increases, the volume resistivity and the electrical breakdown strength show a little decline, while the dielectric constant of the hybrid films increases, which could be attributed to the significant interfacial zone between the polyimide and the filler.
|Uncontrolled Keywords:||Polyimide; Nanocomposites; Electrical properties|
|Subjects:||Material Science > Nanostructured materials|
|Deposited On:||09 Feb 2010 10:13|
|Last Modified:||09 Feb 2010 10:13|
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