Nano Archive

Hierarchically structured superhydrophobic coatings fabricated by successive Langmuir-Blodgett deposition of micro-/nano-sized particles and surface silanization

Tsai, Ping-Szu and Yang, Yu-Min and Lee, Yuh-Lang (2007) Hierarchically structured superhydrophobic coatings fabricated by successive Langmuir-Blodgett deposition of micro-/nano-sized particles and surface silanization. NANOTECHNOLOGY, 18 (46).

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Official URL: http://www.iop.org/EJ/abstract/-search=66090115.1/...

Abstract

The present study demonstrates the creation of a stable, superhydrophobic surface by coupling of successive Langmuir-Blodgett (LB) depositions of micro- and nano-sized (1.5 mu m/50 nm, 1.0 mu m/50 nm, and 0.5 mu m/50 nm) silica particles on a glass substrate with the formation of a self-assembled monolayer of dodecyltrichlorosilane on the surface of the particulate film. Particulate films, in which one layer of 50 nm particles was deposited over one to five sublayers of larger micro- sized particles, with hierarchical surface roughness and superhydrophobicity, were successfully fabricated. Furthermore, the present `two-scale' (micro- and nano-sized particles) approach is superior to the previous `one-scale' (micro- sized particles) approach in that both higher advancing contact angle and lower contact angle hysteresis can be realized. Experimental results revealed that the superhydrophobicity exhibited by as-fabricated particulate films with different sublayer particle diameters increases in the order of 0.5 mu m > 1.0 mu m > 1.5 mu m. However, no clear trend between sublayer number and surface superhydrophobicity could be discerned. An explanation of superhydrophobicity based on the surface roughness introduced by two-scale particles is also proposed.

Item Type:Article
Uncontrolled Keywords:SUPER-HYDROPHOBIC SURFACES; CONTACT-ANGLE HYSTERESIS; PLASMA; WETTABILITY; FILMS; POLY(TETRAFLUOROETHYLENE); POLYPROPYLENE; MONOLAYER; BEHAVIOR; CREATION
Subjects:Material Science > Nanofabrication processes and tools
ID Code:6442
Deposited By:IoN
Deposited On:24 Sep 2009 11:14
Last Modified:24 Sep 2009 11:14

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