Koole, Rolf and Allan, Guy and Delerue, Christophe and Meijerink, Andries and Vanmaekelbergh, Daniel and Houtepen, Arjan J. (2008) Optical investigation of quantum confinement in PbSe nanocrystals at different points in the Brillouin zone. SMALL, 4 (1). pp. 127-133.
Full text is not hosted in this archive but may be available via the Official URL, or by requesting a copy from the corresponding author.
Official URL: http://www3.interscience.wiley.com/journal/1178692...
We present detailed investigations on the optical properties of PbSe nanocrystals. The absorption spectra of monodisperse, quasispherical nanocrystals exhibit sharp features as a result of distinct optical transitions. To study the size dependence, absorption spectra of nanocrystals ranging from 3.4 to 10.9 nm in diameter are analysed and a total of 11 distinct optical transitions are identified. The assignment of the various optical transitions is discussed and compared to theoretically calculated transition energies. By plotting all transitions as a function of nanocrystal size (D) we find that the energy (E) changes with the following relationship ED-1.5 for the lowest energy transitions. The transition energy extrapolates to approximately 0.3 eV for infinite crystal size, in agreement with the bandgap of bulk PbSe at the L-point in the Brillouin zone. In addition, high-energy transitions are observed, which extrapolate to 1.6 eV for infinite crystal size, which is in good agreement with the bulk bandgap of PbSe at the -point in the Brillouin zone. Tight-binding calculations confirm that the high-energy transitions originate from the -point in the Brillouin zone. The -character of the high-energy transitions may be of importance to explain the mechanism behind multiple exciton generation in PbSe nanocrystals.
|Uncontrolled Keywords:||chalcogenides; multiple exciton generation; quantum dots; size-dependent properties; UV/Vis spectroscopy|
|Subjects:||Physical Science > Quantum phenomena|
|Deposited On:||11 Sep 2009 09:26|
|Last Modified:||11 Sep 2009 09:26|
Repository Staff Only: item control page