Navaladian, S. and Viswanathan, B. and Varadarajan, T. K and Viswanath, R. P (2007) Microwave-assisted rapid synthesis of anisotropic Ag nanoparticles by solid state transformation. NANOTECHNOLOGY, 2 (3). pp. 175-183. ISSN 0957-4484 (Print); 1361-6528 (Online)
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Official URL: http://iopscience.iop.org/0957-4484/
Anisotropic silver nanoparticles (NPs) have been synthesized rapidly using microwave irradiation by the decomposition of silver oxalate in a glycol medium using polyvinyl pyrolidone (PVP) as the capping agent. The obtained Ag nanoparticles have been characterized by UV–visible spectroscopy, powder x-ray diffraction (XRD), transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) studies. Anisotropic Ag nanoparticles of average size around 30 nm have been observed in the case of microwave irradiation for 75 s whereas spherical particles of a size around 5–6 nm are formed for 60 s of irradiation. The texture coefficient and particle size calculated from XRD patterns of anisotropic nanoparticles reveal the preferential orientation of (111) facets in the Ag sample. Ethylene glycol is found to be a more suitable medium than diethylene glycol. A plausible mechanism has been proposed for the formation of anisotropic Ag nanoparticles from silver oxalate.
|Subjects:||Physical Science > Nanophysics|
Physical Science > Nano objects
Material Science > Nanochemistry
Material Science > Nanostructured materials
|Divisions:||Faculty of Engineering, Science and Mathematics > School of Physics|
Faculty of Engineering, Science and Mathematics > School of Chemistry
|Deposited On:||11 Aug 2009 07:20|
|Last Modified:||11 Aug 2009 07:20|
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