Serena, S and Caballero, A and Turrillas, X and Martin, D and Sainz, M. A. (2009) Effect of ceramic nanoparticles on the solid-state reaction mechanism of dolomite–zirconium oxide followed by neutron thermodiffraction measurements. Journal of Nanoparticle Research, 11 (4). pp. 869-878.
Full text is not hosted in this archive but may be available via the Official URL, or by requesting a copy from the corresponding author.
Official URL: http://www.springerlink.com/content/b602q015039574...
Abstract
Calcium zirconate–magnesium oxide material was obtained by solid-state reaction from mixed dolomite (CaMg(CO3)2) and zirconia (m-ZrO2) nanopowders. The nanopowders were obtained by high-energy milling, which produced an increase of the superficial free energy of the particles. The role of nanoparticles in the reaction process of monoclinic-zirconia and dolomite was analysed for the first time using neutron thermodiffraction and differential thermal analysis-thermogravimetric techniques. The neutron thermodiffraction of this mixture provides a clear description in situ of the different decomposition and reaction processes that occur in the nanopowders mixture. The results make it possible to analyze the effect of the nanoparticles on the reaction behaviour of these materials.
| Item Type: | Article |
|---|---|
| ID Code: | 4528 |
| Deposited By: | Prof. Alexey Ivanov |
| Deposited On: | 08 May 2009 06:19 |
| Last Modified: | 08 May 2009 10:20 |
Repository Staff Only: item control page
