Raina, G. and Kulkarni, G. U. (2001) A molecular beam study of water–methanol clusters. Chemical Physics Letters, 337 (4-6). pp. 269-276.
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Clusters generated by injecting vapor from water–methanol liquid mixtures of varying compositions through a pulsed valve, have been analyzed using a time-of-flight mass spectrometer. Neat clusters of water and methanol as well as mixed species have been observed, the relative populations varying with composition. The mole fractions in the vapor deviate significantly from the values calculated assuming ideality of the liquid except at water mole fraction of 0.67, the composition around which the excess enthalpy is minimum. An anomaly observed in the cluster populations at this composition is related to an extended hydrogen bonded interaction of molecules in the liquid.
|Subjects:||Material Science > Nanofabrication processes and tools|
|Divisions:||Faculty of Engineering, Science and Mathematics > School of Physics|
Faculty of Engineering, Science and Mathematics > School of Chemistry
|Deposited On:||03 Apr 2009 06:34|
|Last Modified:||03 Apr 2009 06:34|
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