Mukherjee, Partha Sarathi and Das, Neeladri and Stang, Peter J. (2004) Self-Assembly of Nanoscopic Coordination Cages Using a Flexible Tripodal Amide Containing Linker. The Journal of Organic Chemistry, 69 (10). pp. 3526-3529.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo049772u
Flexible, nanoscopic 3D cages containing the amide functionality were prepared via coordination-driven self-assembly from palladium(II) based 90° ditopic acceptor units and a tripod N,N‘,N‘ ‘-tris(3-pyridyl)trimesic amide. Both cages were characterized by NMR (31P, 1H) and electrospray ionization mass spectrometry. An MM2 force field simulation of one cage showed that the shape is likely pseudo trigonal bipyramidal with the diameter of the inner cavity of the cage about 1.9 nm.
|Subjects:||Material Science > Nanofabrication processes and tools|
Material Science > Nanochemistry
Material Science > Nanostructured materials
|Divisions:||Faculty of Engineering, Science and Mathematics > School of Physics|
Faculty of Engineering, Science and Mathematics > School of Chemistry
|Deposited On:||02 Feb 2009 05:52|
|Last Modified:||02 Feb 2009 05:52|
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