Ghosh, Sushobhan and Mukherjee, Partha Sarathi (2007) Self-assembly of metal-organic hybrid nanoscopic rectangles. Dalton Transactions, ( 24 ). pp. 2542-2546.
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The combination of an amide containing a linear ligand ( L1) and an organometallic molecular clip (clip- 1) leads to the self-assembly of a Pt4 nanoscopic framework representing the first example of a Pt-based molecular rectangle (rectangle- 1) incorporating amide functionality. A complementary approach was also followed to prepare a Pd(II)-based molecular rectangle (rectangle- 2) by reaction of a donor organic rigid clip (clip- 2) and trans-(PEt3)2Pd(OTf)2 as the linear metal acceptor ( L2). The Pd(II)-rectangle was characterised by multinuclear NMR and ESI-mass spectroscopy.
|Subjects:||Analytical Science > Microscopy and probe methods|
Material Science > Functional and hybrid materials
Physical Science > Nano objects
Physical Science > Quantum phenomena
Material Science > Nanochemistry
Material Science > Nanostructured materials
|Divisions:||Faculty of Engineering, Science and Mathematics > School of Physics|
Faculty of Engineering, Science and Mathematics > School of Chemistry
|Deposited On:||27 Jan 2009 04:12|
|Last Modified:||27 Jan 2009 04:12|
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