Nano Archive

Self-assembly of metal-organic hybrid nanoscopic rectangles

Ghosh, Sushobhan and Mukherjee, Partha Sarathi (2007) Self-assembly of metal-organic hybrid nanoscopic rectangles. Dalton Transactions, ( 24 ). pp. 2542-2546.

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Official URL: http://www.rsc.org/publishing/journals/DT/article....

Abstract

The combination of an amide containing a linear ligand ( L1) and an organometallic molecular clip (clip- 1) leads to the self-assembly of a Pt4 nanoscopic framework representing the first example of a Pt-based molecular rectangle (rectangle- 1) incorporating amide functionality. A complementary approach was also followed to prepare a Pd(II)-based molecular rectangle (rectangle- 2) by reaction of a donor organic rigid clip (clip- 2) and trans-(PEt3)2Pd(OTf)2 as the linear metal acceptor ( L2). The Pd(II)-rectangle was characterised by multinuclear NMR and ESI-mass spectroscopy.

Item Type:Article
Subjects:Analytical Science > Microscopy and probe methods
Material Science > Functional and hybrid materials
Physical Science > Nano objects
Physical Science > Quantum phenomena
Material Science > Nanochemistry
Material Science > Nanostructured materials
Divisions:Faculty of Engineering, Science and Mathematics > School of Physics
Faculty of Engineering, Science and Mathematics > School of Chemistry
ID Code:3909
Deposited By:JNCASR
Deposited On:27 Jan 2009 04:12
Last Modified:27 Jan 2009 04:12

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