Dagan-Moscovich, Hila and Cohen-Hadar, Noa and Porat, Carmit and Rishpon, Judith and Shacham-Diamand, Yosi and Freeman, Amihay (2007) Nanowiring of the catalytic site of novel molecular enzyme-metal hybrids to electrodes. JOURNAL OF PHYSICAL CHEMISTRY C, 111 (15). pp. 5766-5769.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp066100u
Directed deposition of silver on the surface of single, soluble enzyme molecules was made possible by controlled conjugation of new silver-reducing moieties to the surface of the enzyme molecule and their reaction with silver ions. Molecular enzyme-silver hybrids carrying low or high crystalline silver deposited on their surface were obtained, retaining their solubility and enzymatic activity. The feasibility of ``wiring'' of the active site of glucose oxidase-silver hybrid thus obtained to platinum electrode was readily demonstrated enabling glucose determination in the absence of oxygen.
|Subjects:||Material Science > Nanofabrication processes and tools|
Biomedical Science > Nanobiotechnology
|Deposited By:||Farnush Anwar|
|Deposited On:||16 Jan 2009 14:56|
|Last Modified:||29 Jan 2009 11:21|
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