Zhang, Yi and Ye, Daoli and Gao, Xiang and Liu, Wei and Li, Fangfang (2007) Study of alpha-, beta- and gamma-cyclodextrin/C-60 supramolecular complexes: Influence of the cavity dimension toward the host-guest complexes. FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 15 (5). pp. 317-330.
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Herein we report the spectroscopic, electrochemical, TEM and DLS characterizations Of C-60 supramolecular inclusion complexes with alpha-, beta- and gamma-cyclodextrins prepared using anionic C-60. The results indicate that the cyclodextrin itself has little effect on the encapsulated C-60 or on the properties of the inclusion complex. Instead, the cyclodextrin has a significant influence on the aggregation behavior of individual complex in aqueous solution, which in turn affects the property of the supramolecular complex of cyclodextrin and C-60 greatly, As the cavity dimension of cyclodextrin becomes smaller as it changes from gamma-CD to beta-CD, and finally to alpha-CD, it is observed that more aggregation occurs for the corresponding inclusion complex in aqueous solution.
|Uncontrolled Keywords:||aggregation; cyclodextrin; fullerene; supramolecular chemistry|
|Subjects:||Analytical Science > Microscopy and probe methods|
Physical Science > Nano objects
Material Science > Nanostructured materials
|Deposited By:||Farnush Anwar|
|Deposited On:||12 Jan 2009 10:58|
|Last Modified:||23 Jan 2009 10:41|
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