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Sonochemical reaction of fullerene[C-60] with several 2 `-azidoethyl per-O-acetyl glycosides

Yoon, Shinsook and Hwang, Sung Ho and Ko, Weon Bae (2008) Sonochemical reaction of fullerene[C-60] with several 2 `-azidoethyl per-O-acetyl glycosides. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 8 (6). pp. 3136-3141.

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Cycloadditive reaction of fullerene[C-60] with various 2'-azidoethyl per-O-acetyl glycopyranoside of D-mannose, D-galactose, D-glucose, D-xylose and D-maltose, respectively gave the glycosyl fullerene[C-60] derivatives 2a-2e such as a-D-mannosyl fullerene[C-60] under ultrasonication. Based on analyses using H-1- and C-13-NMR, UV-vis, FT-IR, and FAB-MS spectroscopies of the glycosyl fullerene[C-60] derivatives, the products were composed of a mixture of [5,6]- and [6,6]-junction isomers which were predominantly the closed [5,6]-junction isomer.

Item Type:Article
Uncontrolled Keywords:cycloadditive reaction; fullerene[C-60]; 2 `-azidoethyl per-O-acetyl glycosides; ultrasonication
Subjects:Analytical Science > Microscopy and probe methods
Material Science > Functional and hybrid materials
ID Code:2861
Deposited By:Farnush Anwar
Deposited On:13 Jan 2009 14:11
Last Modified:26 Jan 2009 16:53

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