Meier, Christoph and Landfester, Katharina and Ziener, Ulrich (2008) Topological selectivity in a supramolecular self-assembled host-guest network at the solid-liquid interface. JOURNAL OF PHYSICAL CHEMISTRY C, 112 (39). pp. 15236-15240.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp804235a
An oligopyridine forms a well-ordered two-dimensional network at the graphite-liquid interface stabilized by weak hydrogen bonds. This network offers two types of geometrically different voids of similar size, oval and circular in shape, respectively. Hierarchical coadsorption of C-60 fullerene onto the oligopyridine monolayer leads to a host-guest network in which the fullerene molecules adsorb exclusively in the circularly shaped voids. This is attributed to the fit of the spherical molecules to the round void according to a geometric lock-and-key principle.
|Subjects:||Physical Science > Nano objects|
Material Science > Nanochemistry
|Deposited By:||Farnush Anwar|
|Deposited On:||09 Jan 2009 16:37|
|Last Modified:||09 Jan 2009 16:37|
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