Galloni, Pierluca and Floris, Barbara and De Cola, Luisa and Cecehetto, Elio and Williams, Rene M. (2007) Zinc 5,10,15,20-meso-tetraferrocenylporphyrin as an efficient donor in a supramolecular fullerene C-60 system. JOURNAL OF PHYSICAL CHEMISTRY C, 111 (3). pp. 1517-1523.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp064307h
The supramolecular assembly containing an electron donor, zinc 5,10,15,20-meso-tetraferrocenylporphyrin, and a pyridine-substituted fulleropyrrolidine as an electron acceptor, has been investigated. A comparison of the photophysical properties of the separate components and of the assembled system revealed a photoinduced electron-transfer process from the porphyrin to the fullerene unit. Time-resolved spectroscopy, on the subpicosecond time scale, was performed to determine the rate of the forward and back electron-transfer reactions.
|Subjects:||Analytical Science > Microscopy and probe methods|
Material Science > Nanofabrication processes and tools
Physical Science > Nano objects
|Deposited By:||Farnush Anwar|
|Deposited On:||13 Jan 2009 13:20|
|Last Modified:||26 Jan 2009 16:33|
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