Nano Archive

Adsorption of polar and nonpolar organic chemicals to carbon nanotubes

Chen, Wei and Duan, Lin and Zhu, Dongqiang (2007) Adsorption of polar and nonpolar organic chemicals to carbon nanotubes. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 41 (24). pp. 8295-8300.

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Understanding adsorptive interactions between organic contaminants and carbon nanotubes is critical to both the environmental application of carbon nanotubes as special adsorbents and the assessment of the potential impact of carbon nanotubes on the fate and transport of organic contaminants in the environment. The adsorption of organic compounds with varied physical-chemical properties (hydrophobicity, polarity, electron polarizability, and size) to one single-walled carbon nanotube (SWNT) and two multiwalled carbon nanotubes (MWNTs) was evaluated. For a given carbon nanotube, the adsorption affinity correlated poorly with hydrophobicity but increased in the order of nonpolar aliphatic < nonpolar aromatics < nitroaromatics, and within the group of nitroaromatics, the adsorption affinity increased with the number of nitrofunctional groups. We propose that the strong adsorptive interaction between carbon nanotubes and nitroaromatics was due to the pi - pi electron-donor-acceptor (EDA) interaction between nitroaromatic molecules (electron acceptors) and the highly polarizable graphene sheets (electron donors) of carbon nanotubes. Additionally, we attribute the stronger adsorption of nonpolar aromatics compared to that of nonpolar aliphatics to the pi-electron coupling between the flat surfaces of both aromatic molecules and carbon nanotubes. For tetra chlorobenzene, the bulkiest adsorbate, adsorption affinity (on a unit surface area basis) to the SWNT was much stronger than to the two MWNTs, indicating a probable molecular sieving effect.

Item Type:Article
Subjects:Technology > Nanotechnology and environmental applications
Physical Science > Nanoelectronics
ID Code:242
Deposited By:Lesley Tobin
Deposited On:18 Dec 2008 11:35
Last Modified:05 Jan 2009 13:04

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