Vuorema, Anne and Shariki, Sara and Sillanpää, Mika and Thielemans, Wim and Nelson, Geoffrey W. and Foord, John S. and Dale, Sara E.C. and Bending, Simon and Marken, Frank (2011) Enhanced TiO2 surface electrochemistry with carbonised layer-by-layer cellulose-PDDA composite films. Physical chemistry chemical physics : PCCP, 13 . pp. 9857-9862. ISSN 1463-9076
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2011...
In this report we demonstrate a versatile (and potentially low-cost) cellulose nano-whisker-based surface carbonisation method that allows well-defined films of TiO2 nanoparticles surface-modified with carbon to be obtained. In a layer-by-layer electrostatic deposition process based on TiO2 nanoparticles, cellulose nano-whiskers, and poly(diallyl-dimethylammonium) or PDDA are employed to control the ratio of surface carbon to TiO2. Characterisation based on optical, AFM, XRD, and XPS methods is reported. Electrochemical measurements suggest improved access to surface states, dopamine binding at the anatase surface, and surface redox cycling aided by the thin amorphous carbon film in mesoporous TiO2. In future, the amorphous carbon layer method could be applied for surface processes for a wider range of semiconductor or insulator surfaces
|Subjects:||Material Science > Nanochemistry|
Material Science > Nanostructured materials
|Deposited By:||Prof. Mika Sillanpää|
|Deposited On:||18 Jan 2012 08:23|
|Last Modified:||18 Jan 2012 08:23|
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