Zhang, Qiaohong and Chen, Chen and Wang, Min and Cai, Jiaying and Xu, Jie and Xia, Chungu (2011) Facile preparation of highly-dispersed cobalt-silicon mixed oxide nanosphere and its catalytic application in cyclohexane selective oxidation. NANOSCALE RESEARCH LETTERS, 6 (1). pp. 1-7. ISSN 1931-7573 (Print) 1556-276X (Online)
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Official URL: http://www.nanoscalereslett.com/content/6/1/586
Highly dispersed cobalt-silicon mixed oxide [Co-SiO2] nanosphere was successfully prepared with a modified reverse-phase microemulsion method. This material was characterized in detail by X-ray diffraction, transmission electron microscopy, Fourier transform infrared, ultraviolet-visible diffuse reflectance spectra, X-ray absorption spectroscopy near-edge structure, and N2 adsorption-desorption measurements. High valence state cobalt could be easily obtained without calcination, which is fascinating for the catalytic application for its strong oxidation ability. In the selective oxidation of cyclohexane, Co-SiO2 acted as an efficient catalyst, and good activity could be obtained under mild conditions.
|Subjects:||Material Science > Nanochemistry|
|Deposited By:||M T V|
|Deposited On:||05 Jan 2012 10:34|
|Last Modified:||05 Jan 2012 10:34|
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