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In-situ optical spectroscopy and electronic properties of pyrrole sub-monolayers on Ga-rich GaAs(001)

Bruhn, Thomas and Ewald, Marcel and Fimland, Bjørn-Ove and Kneissl, Michael and Esser, Norbert and Vogt, Patrick (2011) In-situ optical spectroscopy and electronic properties of pyrrole sub-monolayers on Ga-rich GaAs(001). Journal of Nanoparticle Research, 13 (11). pp. 5847-5853.

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Abstract

We report on the characterization of sub-monolayers of pyrrole adsorbed on Ga-rich GaAs(001) surfaces. The interfaces were characterized by scanning tunneling microscopy (STM), scanning tunneling spectroscopy (STS) and reflectance anisotropy spectroscopy (RAS) in a spectral range between 1.5 and 8 eV. The adsorption of pyrrole on Ga-rich GaAs(001) modifies the RAS spectrum of the clean GaAs surface significantly at the surface transitions at 2.2 and 3.5 eV indicating a chemisorption of the molecules. By the help of transients at these surface transitions during the adsorption process, we were able to prepare different molecular coverages from a sub-monolayer up to a complete molecular layer. The different coverages of pyrrole were imaged by STM and electronically characterized by STS. The measurements reveal that the adsorbed molecules electronically insulate the surface and indicate the formation of new interface states around −3.5 and +4.2 eV. The RAS measurements in the UV region show new anisotropies in the spectral range of the optical transitions of the adsorbed pyrrole molecules. Our measurements demonstrate the potential of optical and electronic spectroscopy methods for the characterization of atomically thin molecular layers on semiconductor surfaces allowing a direct access to the properties of single adsorbed molecules.

Item Type:Article
ID Code:11529
Deposited By:Prof. Alexey Ivanov
Deposited On:05 Jan 2012 09:30
Last Modified:05 Jan 2012 09:42

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