Vitale, Floriana and Fratoddi, Ilaria and Battocchio, Chiara and Piscopiello, Emanuela and Tapfer, Leander and Russo, Maria Vittoria and Polzonetti, Giovanni and Giannini, Cinzia (2011) Mono- and bi-functional arenethiols as surfactants for gold nanoparticles: synthesis and characterization. Nanoscale Research Letters, 6 (1). pp. 1-9.
Official URL: http://www.nanoscalereslett.com/content/6/1/103
Stable gold nanoparticles stabilized by different mono and bi-functional arenethiols, namely, benzylthiol and 1,4-benzenedimethanethiol, have been prepared by using a modified Brust's two-phase synthesis. The size, shape, and crystalline structure of the gold nanoparticles have been determined by high-resolution electron microscopy and full-pattern X-ray powder diffraction analyses. Nanocrystals diameters have been tuned in the range 2 Ã· 9 nm by a proper variation of Au/S molar ratio. The chemical composition of gold nanoparticles and their interaction with thiols have been investigated by X-ray photoelectron spectroscopy. In particular, the formation of networks has been observed with interconnected gold nanoparticles containing 1,4-benzenedimethanethiol as ligand.
|Subjects:||Physical Science > Nanophysics|
Physical Science > Nano objects
Material Science > Nanochemistry
Material Science > Nanostructured materials
|Divisions:||Faculty of Engineering, Science and Mathematics > School of Physics|
Faculty of Engineering, Science and Mathematics > School of Chemistry
|Deposited On:||19 Oct 2011 07:11|
|Last Modified:||19 Oct 2011 07:11|
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