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Microwave-assisted polyol synthesis of Cu nanoparticles

Blosi, M. and Albonetti, S. and Dondi, M. and Martelli, C. and Baldi, G. (2011) Microwave-assisted polyol synthesis of Cu nanoparticles. Journal of Nanoparticle Research, 13 (1). pp. 127-138.

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Official URL: http://www.springerlink.com/content/20276035t598h6...

Abstract

Microwave heating was applied to synthesize copper colloidal nanoparticles by a polyol method that exploits the chelating and reducing power of a polidentate alcohol (diethylenglycol). The synthesis was carried out in the presence of eco-friendly additives such as ascorbic acid (reducing agent) and polyvinylpirrolidone (chelating polymer) to improve the reduction kinetics and sols stability. Prepared suspensions, obtained with very high reaction yield, were stable for months in spite of the high metal concentration. In order to optimize suspensions, synthesis parameters were modified and the effects on particle size, optical properties, and reaction yield were investigated. XRD analysis, scanning transmission electron microscopy (STEM), and DLS measurements confirmed that prepared sols consist of crystalline metallic copper with a diameter ranging from 45 to 130 nm. Surface plasmon resonance (SPR) of Cu nanoparticles was monitored by UV–Vis spectroscopy and showed both a red shift and a band weakening due to nanoparticle diameter increase. Microwave use provides rapid, uniform heating of reagents and solvent, while accelerating the reduction of metal precursors and the nucleation of metal clusters, resulting in monodispersed nanostructures. The proposed microwave-assisted synthesis, also usable in large-scale continuous production, makes process intensification possible.

Item Type:Article
Subjects:Physical Science > Nanophysics
Physical Science > Nano objects
Material Science > Nanochemistry
Material Science > Nanostructured materials
Divisions:Faculty of Engineering, Science and Mathematics > School of Physics
Faculty of Engineering, Science and Mathematics > School of Chemistry
ID Code:10578
Deposited By:JNCASR
Deposited On:28 Feb 2011 06:35
Last Modified:28 Feb 2011 06:35

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