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Morphology and magnetic properties of island-like Co and Ni films obtained by de-wetting

Tiberto, P. and Gupta, S. and Bianco, S. and Celegato, F. and Martino, P. and Chiolerio, A. and Tagliaferro, A. and Allia, P. (2011) Morphology and magnetic properties of island-like Co and Ni films obtained by de-wetting. Journal of Nanoparticle Research, 13 (1). pp. 245-255.

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Official URL: http://www.springerlink.com/content/0w0r63w1946322...

Abstract

The morphological, structural, and magnetic properties of Co and Ni films of different thicknesses grown by RF sputtering on a Si-SiO substrate and submitted to controlled diffusion of atoms on the substrate (de-wetting) are studied through X-ray diffraction (XRD), atomic force microscopy, X-ray photoelectron spectroscopy, and alternating-gradient magnetometry. For both metals, de-wetting treatment leads to the growth of non-percolating, metallic nanoislands characterized by a distribution of sizes and aspect ratios. XRD spectra reveal a polycrystalline multi-component structure evolving by effect of de-wetting and directly affecting the magnetic properties of films. The magnetic response after de-wetting is consistent with the formation of a nanogranular magnetic phase characterized by a complex, thickness-dependent magnetic behavior originating from the simultaneous presence of superparamagnetic and blocked-particle contributions. At intermediate film thickness (around 10 nm), a notable enhancement in magnetic coercivity is observed for both metals with respect to the values measured in precursor films and in their bulk counterparts.

Item Type:Article
Subjects:Physical Science > Nanophysics
Physical Science > Nanomagnetics
Divisions:Faculty of Engineering, Science and Mathematics > School of Engineering Sciences
Faculty of Engineering, Science and Mathematics > School of Chemistry
ID Code:10560
Deposited By:JNCASR
Deposited On:30 Apr 2011 12:16
Last Modified:30 Apr 2011 12:16

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